Isopropyl 2-[2-(2,6-dichloroanilino)phenyl]acetate
نویسندگان
چکیده
In the title compound, C(17)H(17)Cl(2)NO(2), the NH group exhibits an intra-molecular hydrogen bond to the carbonyl O atom and no inter-molecular hydrogen bonding, in contrast with previous studies. The dihedral angle between the two benzene rings is 58.57 (5)°. The ester group is planar, the greatest deviation from planarity being 0.0135 (11) Å for the ether O atom.
منابع مشابه
2-[2-(2,6-Dichloroanilino)phenyl]-N-[(2S)-2-methyl-3-oxo-8-phenyl-1-thia-4-azaspiro[4.5]dec-4-yl]acetamide
In the title compound, C(29)H(29)Cl(2)N(3)O(2)S, the phenyl ring is disordered over two orientations with occupancies of 0.55 (3) and 0.45 (3). The mol-ecular packing in the crystal is stabilized by inter-molecular N-H⋯O inter-actions, linking the mol-ecules into infinite chains along the c axis. In addition, there are weak C-H⋯S and C-H⋯π inter-actions.
متن کاملTetrakis{2-[2-(2,6-dichloroanilino)phenyl]ethanoato-κ2 O:O′}bis[(dimethyl sulfoxide-κO)copper(II)](Cu—Cu): a binuclear CuII complex with the non-steroidal anti-inflammatory drug diclofenac
The title compound, [Cu(2)(C(14)H(10)Cl(2)NO(2))(4)(C(2)H(6)OS)(2)], comprises a Cu(II) (2) core that is quadruply bridged by four carboxyl-ate ligands with the dimethyl sulfoxide ligands binding along the Cu⋯Cu axis. The four carboxyl-ate ligands bind in a bidentate syn-syn bridging mode. Mol-ecules reside on crystallographic inversion centres bis-ecting the mid-point of the Cu⋯Cu axis. There ...
متن کامل2-[2-(2,6-Dichloroanilino)phenyl]-N′-(4-propylcyclohexylidene)acetohydrazide
The asymmetric unit of the title compound, C(23)H(27)Cl(2)N(3)O, contains two crystallographically independent mol-ecules in which the dihedral angles between the benzene rings are 70.1 (3) and 63.8 (3)°. In each mol-ecule an intra-molecular N-H⋯O hydrogen bond generates an S(7) ring. The atoms of the propyl grouping of one mol-ecule are disordered over two orientations with occupancies of 0.66...
متن کاملMethyl 2-[2-(2,6-dichloroanilino)phenyl]acetate
In the title compound, C(15)H(13)Cl(2)NO(2), the dihedral angle between the aromatic rings is 63.80 (12)°. The conformation may be stabilized by a weak N-H⋯O hydrogen bond. In the crystal structure, a short C-Cl⋯π interaction occurs, with a Cl⋯π separation of 3.5706 (13) Å.
متن کامل{N′,N′′-Bis[2,6-bis(1-methylethyl)phenyl]-N,N-dimethylguanidinato-κ2 N′,N′′}dibromidoborane
In the mol-ecular structure of the title compound, C(27)H(40)N(3)BBr(2), the B atom is connected to two bromide substituents and a guanidinate scaffold, forming a four-membered ring. An aryl group is connected to each N atom in the ring that contains two isopropyl groups in positions 2 and 6.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007